You could also match the length of both vectors by filling the shortest with NA and merge them as a data frame
h25=seq(663.35,664.03,0.01)
h05=seq(663.49,664.05,0.01)
length(h05) <- length(h25)
cbind(h25,h05)
#> h25 h05
#> [1,] 663.35 663.49
#> [2,] 663.36 663.50
#> [3,] 663.37 663.51
#> [4,] 663.38 663.52
#> [5,] 663.39 663.53
#> [6,] 663.40 663.54
#> [7,] 663.41 663.55
#> [8,] 663.42 663.56
#> [9,] 663.43 663.57
#> [10,] 663.44 663.58
#> [11,] 663.45 663.59
#> [12,] 663.46 663.60
#> [13,] 663.47 663.61
#> [14,] 663.48 663.62
#> [15,] 663.49 663.63
#> [16,] 663.50 663.64
#> [17,] 663.51 663.65
#> [18,] 663.52 663.66
#> [19,] 663.53 663.67
#> [20,] 663.54 663.68
#> [21,] 663.55 663.69
#> [22,] 663.56 663.70
#> [23,] 663.57 663.71
#> [24,] 663.58 663.72
#> [25,] 663.59 663.73
#> [26,] 663.60 663.74
#> [27,] 663.61 663.75
#> [28,] 663.62 663.76
#> [29,] 663.63 663.77
#> [30,] 663.64 663.78
#> [31,] 663.65 663.79
#> [32,] 663.66 663.80
#> [33,] 663.67 663.81
#> [34,] 663.68 663.82
#> [35,] 663.69 663.83
#> [36,] 663.70 663.84
#> [37,] 663.71 663.85
#> [38,] 663.72 663.86
#> [39,] 663.73 663.87
#> [40,] 663.74 663.88
#> [41,] 663.75 663.89
#> [42,] 663.76 663.90
#> [43,] 663.77 663.91
#> [44,] 663.78 663.92
#> [45,] 663.79 663.93
#> [46,] 663.80 663.94
#> [47,] 663.81 663.95
#> [48,] 663.82 663.96
#> [49,] 663.83 663.97
#> [50,] 663.84 663.98
#> [51,] 663.85 663.99
#> [52,] 663.86 664.00
#> [53,] 663.87 664.01
#> [54,] 663.88 664.02
#> [55,] 663.89 664.03
#> [56,] 663.90 664.04
#> [57,] 663.91 664.05
#> [58,] 663.92 NA
#> [59,] 663.93 NA
#> [60,] 663.94 NA
#> [61,] 663.95 NA
#> [62,] 663.96 NA
#> [63,] 663.97 NA
#> [64,] 663.98 NA
#> [65,] 663.99 NA
#> [66,] 664.00 NA
#> [67,] 664.01 NA
#> [68,] 664.02 NA
#> [69,] 664.03 NA
Created on 2019-11-13 by the reprex package (v0.3.0.9000)